59403-81-5Relevant academic research and scientific papers
CATIONIC CYCLIZATION OF GERANONITRILE AND RELATED COMPOUNDS VIA THEIR BROMOHYDRINS: APPLICATION TO THE SYNTHESIS OF (+/-)-SNYDEROLS
Murai, Akio,Abiko, Atsushi,Kato, Koji,Masamune, Tadashi
, p. 1125 - 1128 (2007/10/02)
Cationic cyclization of bromohydrins of geranonitrile and homogeranonitrile in the presence of boron trifluoride complexes proceeded smoothly, giving mixtures of bromo cyclic olefins in satisfactory yields.This cyclization method was applied to the synthesis of (+/-)-snyderols.
Brominative Cyclisation of Nerolidol and Geranyl-linalool
Kato, Tadahiro,Ishii, Koichi,Ichinose, Isao,Nakai, Yoko,Kumagai, Takashi
, p. 1106 - 1108 (2007/10/02)
(+)-Nerolidol was treated with 2,4,4,6-tetrabromocyclohexa-2,5-dienone to afford the brominative cyclisation products α- and β-snyderols and 3-bromocaparrapi oxide and its 8-epimer; (+/-)-geranyl-linalool gave the analogous tricyclic ethers.
