59417-79-7

Upstream product

• 743436-35-3 1-(p-iodophenyl)-2-(2'-thienyl)ethene 
• 98-03-3 thiophene-2-carbaldehyde 
• 624-31-7 4-tolyl iodide 
• 61130-13-0 [(4-iodophenyl)methyl]triphenylphosphanium bromide 

Downstream Products

• 743436-37-5 (E)-1-[4-(3-hydroxy-3-methyl-1-butyn)phenyl]-2-(2'-thienyl)ethene 
• 743436-36-4 1-(p-iodophenyl)-2-(2'-thienyl)ethylene 
• 885325-35-9 1,2-dibromo-1-(p-iodophenyl)-2-(2'-thienyl)ethane 
• 743436-39-7 1-[4-(3-hydroxy-3-methyl-1-butyn)phenyl]-2-(2'-thienyl)ethyne 
• 743436-41-1 (E)-1-(2'-thienyl)-2-(4-bromoethynylphenyl)ethene 
• 264884-57-3 1-(2'-thienyl)-2-(p-ethynylphenyl)ethyne 
• 743436-38-6 (E)-1-(2'-thienyl)-2-(p-ethynylphenyl)ethene 

Relevant academic research and scientific papers

Synthesis of conjugated 2 and 2,5-(ethenyl) and (ethynyl)phenylethynyl thiophenes: Fluorescence properties

Nano conjugated thienylethenyl and thienylethynyl compounds with controlled structure and dimensions have been efficiently prepared, by heterocoupling reaction between 1,4-(thienylethynyl)phenylacetylene (or thienylethenyl) phenylacetylene and 2- or 2,5-dihalothiophene. Conjugated 1,4-di(2- thienylethynylphenyl)- (or 2-thienylethenylphenyl)-1,3-butadiyne were obtained by the homocoupling of the terminal acetylenes in excellent yield. The end-capped (N,N-dimethylaminophenyl)- and [3,5-di(trimethylsilylethynyl)-1- ethynyl]-2,5-di(phenylethynyl)nthiophene were obtained by the heterocoupling between the corresponding terminal acetylene and 2,5-di(iodo)thiophene, catalyzed by the bis(triphenylphosphine)palladium and cuprous iodide system in excellent yield.

Synthesis of conjugated 2-arylethynyl and 2-arylethenyl thiophene structures with optical properties

Conjugated mono(arylethynyl)oligothiophene structures have been obtained starting with (E)-[1-(2′-thienyl)-2-(p-phenyl)]ethyne (E)-7 and 2-[p-(iodophenyl)ethynyl]thiophene 8. Conjugated nanostructures were synthesized by oxidative coupling between the ter