5942-16-5Relevant articles and documents
Fe-mediated synthesis of: N -aryl amides from nitroarenes and acyl chlorides
Wu, Yundong,Guo, Lei,Liu, Yuxuan,Xiang, Jiannan,Jiang, Jun
, p. 15290 - 15295 (2021/05/19)
Amides are prevalent in nature and valuable functional compounds in agrochemical, pharmaceutical, and materials industries. In this work, we developed a selective and mild method for the synthesis of N-aryl amides. Starting from commercially available nitroarenes and acyl halides, N-aryl amides with good yields can be obtained in water. Especially in the process of transformation, Fe dust is the only reductant and additive, and the reaction can be easily performed on a large scale.
Cooperativity of H-bonding and anion-π interaction in the binding of anions with neutral π-acceptors
Giese, Michael,Albrecht, Markus,Krappitz, Tim,Peters, Marius,Gossen, Verena,Raabe, Gerhard,Valkonen, Arto,Rissanen, Kari
supporting information, p. 9983 - 9985 (2012/11/07)
A rare anion-π complex between bromide and a neutral receptor is reported and related receptor systems are studied with a series of anions. The interaction is observed in the solid state and in solution, and further evidence for it is obtained by a computational study. This journal is The Royal Society of Chemistry 2012.