5943-32-8Relevant academic research and scientific papers
Use of a sacriflcial-sulfur electrode in electroorganic chemistry. V. Formation of the sequence CSSSC from S and thiols or thiolates
Do, Quang Tho,Elothmani, Driss,Simonet, Jacques,Guillanton, Georges Le
, p. 273 - 281 (2007/10/03)
At a working potential of about +2.0 V (vs SCE) the carbon-sulfur electrode is a source of the electrogenerated cation S2+. In organic media, this electrophile reacts with thiols (or thiolates) to give a mixture of polysulfides of which the trisulfide is the main product. The reaction between electrogenerated Sy2- and alkyl halides is less selective. Elsevier,.
ACTION OF ELEMENTARY SULFUR ONTO CARBANIONS: A NEW ROUTE TO DIALKYLPOLYSULFIDES
Boscato, J. F.,Catala, J. M.,Franta, E.,Brossas, J.
, p. 1519 - 1520 (2007/10/02)
The reaction of sec-Butyllithium with elemental sulfur leads to the formation of dialkylpolysulfides.
