71204-46-1Relevant academic research and scientific papers
On the preparation of carbohydrate sulfates by displacement of trifluoromethanesulfonates
Hyatt,Little
, p. 215 - 217 (2007/10/02)
This paper reports on the preparation of carbohydrate sulfates by displacement of trifluoromethanesulfonates.
A Convenient Synthesis of 4-Amino-4-desoxy Sugars
Malik, Abdul,Roosz, Michael,Voelter, Wolfgang
, p. 559 - 561 (2007/10/02)
Displacement of the triflyl by the amino group in benzyl-2,3-anhydro-4-triflyl-pyranosides 4-6 gives with inversion the benzyl-2,3-anhydro-4-amino-4-desoxypyranosides 7-9.The triflyl group turns out to be a reactive leaving group which can be replaced by
Synthesis of Sugar Nitrates by Nucloephilic Substitution
Afza, Nighat,Malik, Abdul,Latif, Farzana,Voelter, Wolfgang
, p. 1929 - 1934 (2007/10/02)
A rapid high-yielding synthesis of sugar mono- and dinitrates has been achieved via displacement of the trifluoromethylsulfonyloxy (triflate) by the nitrate group.This procedure is mild, convenient, and does not attack highly acid-labile groups.It also do
C-4-Triflate Displacement by Azide in 2,3-Anhydro Sugars; a New Way to 4-Amino-4-deoxy Sugars
Kimmich, Reinhard,Voelter, Wolfgang
, p. 1100 - 1104 (2007/10/02)
Displacement of the triflyl by the azido group in benzyl-2,3-anhydro-4-triflyl-α-D-pyranosides 4-6 gives with inversion the benzyl-2,3-anhydro-4-azido-4-deoxypyranosides 7-9.The triflyl group turns out to be a reactive leaving group which can be replaced
