5950-21-0Relevant academic research and scientific papers
Photoinduced reactions of chloroacetone in solid Ar: Identification of CH2=COClCH3
Tanaka, Nobuaki,Urashima, Yoshitaka,Nishikiori, Hiromasa
, p. 258 - 262 (2015/02/02)
The UV light-induced reactions of chloroacetone in a cryogenic Ar matrix were investigated using infrared spectroscopy. The photoinduced isomerisations of gauche-chloroacetone to syn-chloroacetone and hypochlorous acid 1-methylethenyl ester were confirmed by comparing the experimental and calculated spectra. In addition, the photolysis products were found to be CH2CO and a cyclopropanone-HCl complex. The cyclopropanone-HCl complex was further decomposed into CH2CH2, CO and HCl. The hypochlorous acid 1-methylethenyl ester was further isomerized to 2-chloro-2-methyloxirane.
Radical Reactions of Epoxides. Chlorine Atom Abstraction from α- and β-Chloro Epoxides by the Triphenyltin Radical
Krosley, Kevin W.,Gleicher, Gerald Jay,Clapp Gary E.
, p. 840 - 844 (2007/10/02)
The four isomers of chloroepoxypropane have been prepared, and their relative reactivities with triphenyltin haydride have been determined.The three α-chloroepoxypropanes react at a much slower rate than does epichlorohydrin, the only β-chloro epoxide of the four.The nature of the increased reactivity for the β-chloro epoxides has been investigated by studying two pair of diastereomeric β-chloro epoxides, and a single acyclic β-chloro ether.The results are discussed in terms of the inductive, and stereoelectronic effects of the epoxide.
