59541-28-5

Upstream product

• 81823-12-3 1,2-O-isopropylidene-3,6-di-O-benzyl-α-D-glucofuranose 

Downstream Products

• 81823-13-4 3,6-di-O-benzyl-1,2-O-isopropylidene-α-D-xylo-hexofuranos-5-ulose (E) 5-p-tolylsulfonylhydrazone 
• 220204-95-5 3,6-di-O-benzyl-5-deoxy-5-dimethoxyphosphinyl-1,2-O-isopropylidene-α-D-galactofuranose 
• 220204-94-4 (5S)-3,6-di-O-benzyl-5-deoxy-5-dimethoxyphosphinyl-1,2-O-isopropylidene-β-L-idofuranose 
• 219901-09-4 (5R)-3,6-di-O-benzyl-5-deoxy-5-dimethoxyphosphinyl-1,2-O-isopropylidene-α-D-glucofuranose 
• 220204-91-1 (5R)-3,6-di-O-benzyl-5-deoxy-5-dimethoxyphosphinyl-1,2-O-isopropylidene-α-D-xylo-hexofuranose 
• 220204-88-6 (5S)-3,6-di-O-benzyl-5-deoxy-5-dimethoxyphosphinyl-1,2-O-isopropylidene-α-D-xylo-hexofuranose 
• 220204-93-3 (5S)-3,6-di-O-benzyl-5-deoxy-5-dimethoxyphosphinyl-1,2-O-isopropylidene-β-L-arabino-hexofuranose 
• 220204-92-2 (5R)-3,6-di-O-benzyl-5-deoxy-5-dimethoxyphosphinyl-1,2-O-isopropylidene-β-L-arabino-hexofuranose 

Relevant academic research and scientific papers

Stereoselectivity in deoxygenation of 5-hydroxy-5-phosphinyl-hexofuranoses (α-hydroxyphosphonates)

The addition of dimethyl phosphonate to six different hexofuranos-5-uloses in the presence of DBU, followed by esterification with methoxalyl chloride and then radical reduction, afforded 5-deoxy-5-dimethoxyphosphinyl-D- and L-hexofuranoses. The stereosel

SYNTHESIS OF 1,2,4-TRI-O-ACETYL-3,6-DI-O-BENZYL-5-DEOXY-5-C--β-D-GLUCOPYRANOSE: THE FIRST gluco TYPE OF HEXOPYRANOSE DERIVATIVE HAVING PHOSPHORUS IN THE HEMIACETAL RING

Oxidation of 3,6-di-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose with pyridinium chlorochromate in the presence of molecular sieves, followed by conversion into the p-tolylsulfonylhydrazone, addition of methyl phenylphosphinate, and reduction with sodi