81823-13-4

Upstream product

• 81823-12-3 1,2-O-isopropylidene-3,6-di-O-benzyl-α-D-glucofuranose 
• 59541-28-5 3,6-di-O-benzyl-1,2-O-isopropylidene-α-D-xylo-hexofuranose-5-ulose 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 

Downstream Products

• 84175-60-0 [2-Benzyloxy-1-((3aR,5S,6R,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethyl]-ethyl-phosphinic acid methyl ester 
• 84175-56-4 (5RS)-3,6-Di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-(ethylmethoxyphosphinyl)-5-C-<(p-tolylsulfonyl)-hydrazino>-α-D-xylo-hexofuranose 
• 81823-15-6 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-5-C-(p-tolylsulfonylhydrazino)-α-D-xylo-hexofuranose 
• 81835-18-9 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-(phenylphosphinyl)-α-D-xylo-hexofuranose 
• 84175-68-8 (3aS,4aR,7aR,7bR)-2-Ethyl-6,6-dimethyl-3-trityloxymethyl-tetrahydro-[1,3]dioxolo[4',5':4,5]furo[2,3-d][1,2]oxaphosphole 2-oxide 
• 81823-16-7 5(R,S)-3,6-di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-<(methoxy)phenylphosphinyl>-α-D-xylo-hexofuranose 
• 81823-18-9 Acetic acid (3R,4S,5S)-3,5-diacetoxy-4-benzyloxy-6-benzyloxymethyl-1-oxo-1-phenyl-1λ⁵-phosphinan-2-yl ester 
• 81823-18-9 1,2,4-tri-O-acetyl-3,6-di-O-benzyl-5-deoxy-5-C-(phenylphosphinyl)-β-D-glucopyranose 
• 84175-60-0 (5RS)-3,6-Di-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-C-(ethylmethoxyphosphinyl)-α-D-xylo-hexofuranose 
• 84175-68-8 (5R)-5-Deoxy-5-C-<(R)-O-cyclo-ethylphosphinyl>-1,2-O-isopropylidene-6-O-(triphenylmethyl)-α-D-xylo-hexofuranose 
• 84175-69-9 (5S)-5-Deoxy-5-C-<(S)-O-cyclo-ethylphosphinyl>-1,2-O-isopropylidene-6-O-(triphenylmethyl)-α-D-xylo-hexofuranose 

Relevant academic research and scientific papers

SYNTHESIS OF 1,2,4-TRI-O-ACETYL-3,6-DI-O-BENZYL-5-DEOXY-5-C--β-D-GLUCOPYRANOSE: THE FIRST gluco TYPE OF HEXOPYRANOSE DERIVATIVE HAVING PHOSPHORUS IN THE HEMIACETAL RING

Oxidation of 3,6-di-O-benzyl-1,2-O-isopropylidene-α-D-glucofuranose with pyridinium chlorochromate in the presence of molecular sieves, followed by conversion into the p-tolylsulfonylhydrazone, addition of methyl phenylphosphinate, and reduction with sodi