595566-02-2Relevant academic research and scientific papers
Indium(I)-catalyzed asymmetric allylation, crotylation, and αchloroallyalation of hydrazones with rare constitutional and high configurational selectivities
Chakrabarti, Ananya,Konishi, Hideyuki,Yamaguchi, Miyuki,Schneider, Uwe,Kobayashi, Shu
supporting information; experimental part, p. 1838 - 1841 (2010/06/17)
The hydra-zone: The first example of asymmetric In catalysis had been developed. In I combined with a chiral semicorrin ligand (L*) is an effective catalyst for enantioselective allylation, crotylation and α-chloroallylation of hydrazones. In the two latter cases, C-C bond formations proceeded with high selectivity where both reactive aliphatic C-Cl and aromatic O-H bonds were tolerated. Chemical equation representation
