5962-57-2

Basic information

• Product Name: bis-(toluene-4-sulfonyl)-disulfane
• Synonyms: bis-(toluene-4-sulfonyl)-disulfane
• CAS NO: 5962-57-2
• Molecular Weight: 374.527
• Mol File: 5962-57-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: bis-(toluene-4-sulfonyl)-disulfane(CAS DataBase Reference)
• NIST Chemistry Reference: bis-(toluene-4-sulfonyl)-disulfane(5962-57-2)
• EPA Substance Registry System: bis-(toluene-4-sulfonyl)-disulfane(5962-57-2)

Safety Data

• Hazardous Substances Data: 5962-57-2(Hazardous Substances Data)

Upstream product

• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 16601-12-0 S-(4-toluenesulfonyl) 4-toluenethiosulfonate 
• 536-57-2 p-toluene sulfinic acid 
• 103-34-4 4,4'-dithiodimorpholine 
• 10220-20-9 1,1'-dithiobispiperidine 
• 28519-50-8 potassium thiotosylate 
• 824-79-3 sodium 4-methylbenzenesulfinate 

Downstream Products

• 16601-12-0 S-(4-toluenesulfonyl) 4-toluenethiosulfonate 
• 5692-44-4 di-p-toluenesulfonyl trisulfide 

Relevant articles and documents

Copper-Catalyzed C5-H Sulfenylation of Unprotected 8-Aminoquinolines Using Sulfonyl Hydrazides

The synthesis of C5-sulfenylated 8-aminoquinolines using unprotected 8-aminoquinolines and sulfonyl hydrazides is achieved via the catalysis of CuI. The reactions are hypothesized to proceed via the Cu(I)-Cu(II)-Cu(I) catalytic processes induced by aerobic oxidation and single-electron transfer on the Cu(II)-8-aminoquinoline complex. This work discloses an unprecedented step-efficient method for the synthesis of C5-sulfenylated 8-aminoquinolines bearing a useful free NH2 group.

REACTIONS OF DIAMINO DISULFIDES, DIAMINO SULFIDES, AND DIAMINO SULFOXIDES WITH p-TOLUENESULFINIC ACID

The reactions of diamino disulfides (2) and diamino sulfides (3) with p-toluenesulfinic acid (1) were found to give new types of compounds, amino p-toluenesulfonyl disulfides (5) and amino p-toluenesulfonyl sulfides (10), respectively.On the other hand, the reaction between dimorpholino sulfoxide (4) and 1 gave p-toluenesulfinylmorpholide (13).