5962-66-3Relevant articles and documents
Thiomethylation of amino alcohols using formaldehyde and hydrogen sulfide
Akhmetova,Nadyrgulova,Tyumkina,Starikova,Antipin,Kunakova,Dzhemilev
, p. 918 - 925 (2008/03/11)
Three-component condensations of formaldehyde with hydrogen sulfide and hydroxylamine or amino alcohols at a ratio of 3:2:1 give 47-73% of N-hydroxy(or hydroxyalkyl)-1,3,5-dithiazinanes. The reactions of CH2O with H 2S and hydroxylamine or α-amino alcohols at a ratio of 4:3:1 involve both amino and hydroxy groups, leading to the corresponding dithiazinanes. 4-Aminobutan-1-ol reacts with CH2O and H2S under analogous conditions only at the amino group to form 4-(1,3,5-dithiazinan- 5-yl)butan-1-ol.