5962-80-1Relevant academic research and scientific papers
Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates
Ping, Yifan,Chang, Taiwei,Wang, Kang,Huo, Jingfeng,Wang, Jianbo
, p. 59 - 62 (2019)
A palladium-catalyzed oxidative borylation reaction of conjugated enynones is developed. This reaction represents a new method for the synthesis of furyl-substituted alkenylboronates. The reaction works well with a series of conjugated enynones. Boryl migratory insertion of the palladium carbene intermediate is proposed as the key step in these transformations.
Gold(I)-catalyzed, stereocontrolled enamide synthesis from primary amides and propargyl aldehydes using a tandem strategy
Kim, Sang Min,Lee, Dabon,Hong, Soon Hyeok
supporting information, p. 6168 - 6171 (2015/01/16)
A novel strategy for enamide synthesis from primary amides and propargyl aldehydes via Au(I)-catalyzed tandem amide addition and Meyer-Schuster rearrangement is described. In situ generated hemiaminals were successfully converted to the desired products u
