59636-00-9

Upstream product

• 87-24-1 ethyl 2-methylbenzoate 
• 603-35-0 triphenylphosphine 
• 7115-91-5 2-ethoxycarbonylbenzyl bromide 

Downstream Products

• 864850-65-7 benzyl 2-[2-[2-(ethoxycarbonyl)phenyl]-1-ethenyl]benzoate 
• 90011-52-2 ethyl 2-(2-nitrostyryl)benzoate 
• 593248-91-0 2-[2-(2-ethoxycarbonylphenyl)-1-ethyl]benzoic acid 
• 67504-57-8 (1SR,1aRS,6aRS)-1-phenyl-1,1a,6,6a-tetrahydrocyclopropa[α]indene 
• 83640-57-7 (E)-2-<2-(N-methylindol-3-yl)ethenyl>benzoic acid 
• 345630-05-9 Ethyl cis-2-<2-(4-nitrophenyl)ethenyl>benzoate 

Relevant academic research and scientific papers

Synthesis of 6H-isoindolo[2,1-a]indol-6-ones through wittig reaction and tandem reductive cyclization-lactamization

A convenient and efficient two-step route to 6H-Isoindolo[2,1-a]indol-6- ones has been developed starting from o-nitrobenzaldehydes. The methodology involves Wittig reaction followed by tandem reductive cyclization-lactamization. A series of isoindoloindo

Thiazolylbenzofuran derivatives and pharmaceutical composition comprising the same

Compounds of the formula: STR1 wherein R1, R2, R3, R4, A, X and Y are as defined and pharmaceutically acceptable salts thereof; which have activities as leukotriene and Slow Reacting Substance of Anaphalaxis (SR

A convenient synthesis of methyl 1-alkoxy-3-perfluoroalkyl-2-naphthoates

Methyl 1-alkoxy-3-perfluoroalkyl-2-naphthoates 5 were synthesized by heating appropriately substituted 2-triphenylphosphoranylidene-2-butenoates 3 in xylenes at 250°C in a sealed tube. Compounds 3 were obtained via an intramolecular Wittig reaction of 2-alkoxycarbonylbenzyltriphenylphosphonium bromide (1) with methyl 2-perfluoroalkynoates 2 in the presence of potassium carbonate.

HELICENES : SYNTHESE PHOTOCHIMIQUE ET ETUDE RMN 19F, 13 C ET 1H DE FLUORO-1-HEXAHELICENES ET FLUORO-1-HEPTAHELICENES.

1-Fluorohexahelicene, 1-fluoroheptahelicene and 12 substituted derivatives of these fluorohelicenes have been synthesized by the photocyclodehydrogenation of 1-fluro-11-styrylbenzophenanthrenes (Table 2) and 1-fluoro-13-styrylpentahelicenes (Table 4) respectively.The photocyclisations to heptahelicenes were accompanied in five cases, by a side reaction, namely a photodefluoration.A new synthesis of heptahelicenes is described (25-->18 : 40 percent). 1H, 19F and 13C-NMR spectra are discussed. 19F and 13C-NMR spectra of 1-fluoro-, 1-fluoro-13-methyl- and 1-fluoro-13-methoxycarbonylpentahelicene (8d, 8a and 8 R=-CO2CH3) are also included.

Microbicidal nitrofuryl compounds

2-[(O-ALKYLAROYLHYDRAZONO)PROPEN-1-YL]-5-NITROFURANS [1] ARE PREPARED BY CONDENSING 3-(5-NITRO-2-FURYL)ACRYLALDEHYDE [2] WITH AN O-ALKYLAROYL HYDRAZIDE [3]. Compounds [1] are bactericides, protozoacides and fungicides and are administrable to animals in therapeutically-acceptable compositions.