59637-33-1

Upstream product

• 693-03-8 n-butyl magnesium bromide 
• 100-52-7 benzaldehyde 
• 627-15-6 1,3-dibromopropene 
• 219547-14-5 3-tert-butyl-2,2-dimethyldec-5-yn-3-ol 
• 693-02-7 hex-1-yne 
• 219547-17-8 (E)-3-tert-butyl-2,2-dimethyldec-5-en-3-ol 

Relevant academic research and scientific papers

Highly diastereoselective reactions using masked allylic zinc reagents

Substituted allylic organozinc reagents have been prepared using a novel fragmentation reaction; the resulting allylic zinc species are configurationally stable and give excellent regio- and diastereo-selectivities.

Reaction of 1,3-dihalopropene with trialkylmanganate

A three-component coupling reaction was performed. Treatment of 1,3-dibromopropene or 1,3-dichloropropene with tributylmanganate (n-Bu3MnLi) provided a butylated allylmanganese compound which could be trapped by an electrophile such as benzalde