596813-87-5Relevant academic research and scientific papers
Rhodium-catalyzed formation of stereocontrolled trisubstituted alkenes from Baylis-Hillman adducts
Gendrineau, Thomas,Demoulin, Nicolas,Navarre, Laure,Genet, Jean-Pierre,Darses, Sylvain
supporting information; experimental part, p. 4710 - 4715 (2009/12/30)
We report here efficient and general conditions for the formation of stereodefined trisubstituted alkenes using the rhodium-catalyzed reaction of unactivated Baylis-Hillman adducts with either organoboronic acids and potassium trifluoro(organo)borates. Th
Rhodium fluorapatite catalyst for the synthesis of trisubstituted olefins via cross coupling of Baylis-Hillman adducts and arylboronic acids
Lakshmi Kantam,Shiva Kumar,Sreedhar
, p. 320 - 322 (2008/04/12)
(Chemical Equation Presented) Treatment of fluorapatite (prepared by incorporating basic species F- in apatite in situ by coprecipitation) with an aqueous solution of RhCl3 resulted in rhodium-exchanged fluorapatite catalyst (RhFAP),
Palladium-Catalyzed Cross-Coupling of Acetates of Baylis-Hillman Adducts and Potassium Organotrifluoroborates
Kabalka, George W.,Venkataiah, Bollu,Dong, Gang
, p. 3803 - 3805 (2007/10/03)
(Matrix presented) The cross-coupling of potassium organotrifluoroborates and acetates of Baylis-Hillman adducts proceeds readily in moderate to excellent yield in the presence of Pd(OAc)2. The reaction tolerates hindered trifluoroborate salts,
