59700-85-5Relevant academic research and scientific papers
Asymmetric transfer hydrogenation of functionalized acetylenic ketones
Fang, Zhijia,Wills, Martin
, p. 8594 - 8605 (2013/09/24)
A systematic study of the asymmetric transfer hydrogenations of functionalized acetylenic ketones and diketones has been completed, together with a total synthesis of (S,S)-(-)-yashabushidiol B. In several cases, excellent enantioselectivities and yields
Synthesis of alkyl alkynyl ketones by Pd/light-induced three-component coupling reactions of iodoalkanes, CO, and 1-alkynes
Fusano, Akira,Fukuyama, Takahide,Nishitani, Satoshi,Inouye, Takaya,Ryu, Ilhyong
supporting information; experimental part, p. 2410 - 2413 (2010/07/17)
Under photoirradiation conditions using xenon light, in the presence of a catalytic amount of PdCl2(PPh3)2 with triethylamine as a base, a three-component coupling reaction of iodoalkanes, carbon monoxide, and terminal alkynes proceeded to give alkyl alkynyl ketones in good yields.
