59736-11-7Relevant academic research and scientific papers
Synthesis of perfluorinated dialkyl ethers from products of reaction of hexafluoropropene dimers with methanol
Moldavskii,Bispen,Furin,Zhuzhgov
, p. 575 - 582 (2007/10/03)
Perfluoro-2-methyl-2-pentene reacts with methanol in tetrahydrofuran and acetone in the presence of KOH to form predominantly the product of fluorine substitution at the double bond, whereas perfluoro-4-methyl-2-pentene reacts with methanol on heating in tetrahydrofuran in the presence of KOH or triethylamine with incorporation of two or three methoxy groups. Gas-phase fluorination of 3-methoxyperfluoro-2-methyl-2-pentene and 3-methoxyperfluoro-2-methylpentane with elemental fluorine on catalysts is studied, and conditions for preparing perfluoro-2-methyl-3-methoxypentane are revealed.
