59748-16-2Relevant academic research and scientific papers
Synthesis and characterization of ferroelectric and antiferroelectric liquid crystals derived from (2S)-2-(6-hydroxy-2-naphthyl)propionic acid
Wu,Chen,Chen,Wang,Shy,Hsiue
, p. 39 - 50 (1995)
A new series of chiral materials, hexyl(2s)-2-(6-(-4-(4′-alkoxyphenyl)benzoyloxy)-2′-naphthyl) propionates (HmPBNP; m = 6-18) had been prepared and their liquid crystalline properties were investigated as a function of alkyl chain length. These chiral materials exhibited novel ferroelectric Sc* and antiferroelectric ScA* phases and a propensity to the formation of the ScA* phase was found at longer alkyl chain lengths (m = 10, 12-18). An odd-even effect of the threshold voltage as a function of alkyl chain length for compounds HmPBNP (m = 12-16) possessing antiferroelectricity was observed. Spontaneous polarization and transverse dipole moment were also measured and are discussed in terms of the elongated alkyl chain length.
Photo and electrically switchable B7 mesophase exhibiting asymmetric bent-core liquid crystals
Srinivasan, Murugesan Vijay,Kannan, Palaninathan,Roy, Arun
, p. 1584 - 1590 (2013/06/04)
The first bent-core liquid crystal materials with a photo-active azo linkage exhibiting the B7 mesophase are reported. The lower homologues of the bent-core compounds display the B1 phase and higher homologues show the B7 mesophase. The mesomorphic properties were characterized using polarized optical microscopy, differential scanning calorimetry and X-ray diffraction. The B7 phase of these materials establishes ferroelectric switching characteristics with anticlinic organization (SmCAPF) of the molecules in the layers. The bent-core molecules with an azo linkage are important for photoisomerization studies, which indicate trans to cis isomerization at 30 s, whereas the reverse processes take place over 40 s in chloroform.
Synthesis and mesomorphic properties of low molar mass phosphorus derivatives
Tokushige,Mihara,Koide
, p. 27 - 38 (2007/10/03)
New liquid crystalline phosphorus derivatives were synthesized as a core model compound and/or a model compound of the component for semiflexible liquid crystalline polymers. Alkoxy, oligo ethylene oxide, or chiral moieties were introduced into the terminal group of rigid moiety in order to investigate the effect of the terminal group on the thermal properties of the phosphorus derivatives. A nematic phase appears for the phosphorus derivative with alkoxy moieties or oligo ethylene oxide chain, while a mesophase is observed for the phosphorus derivative with a chiral moiety. Some phosphorus derivatives were thermally stable until more than 300°C.
Mesomorphic trigonal bipyramidal iron(0) isocyanide complexes
Coco, Silverio,Espinet, Pablo,Marcos, Eva
, p. 1297 - 1302 (2007/10/03)
The synthesis, characterization and mesomorphic properties of three series of isocyanides and their trigonal bipyramidal iron(0) complexes [Fe(CO)4(CNR)] (R= C6H4O(O)CC6H4C6H4OC(n)H2(n)+1, C6H4C(O)OC6H4C6H4OC(n)H2(n)+1, C6H4C6H4O(O)CC6H4OC(n)H2(n)+1, n = 6, 8, 10, 12) are described. The free isocyanides exhibit nematic and/or smectic A phases for shorter chains (n = 6, 8) and only smectic A phases for longer chains, except the isocyanides CNC6H4O(O)CC6H4C6H4OC(n)H2(n)+1 which melt with extensive decomposition and do not produce mesophases. Their coordination to give the iron complexes [Fe(CO)4(CNR)] produces a slight decrease of their transition temperatures. The iron isocyanide complexes prepared show only a smectic C phase. The relationship between the molecular structure of the complexes and their thermal behaviour is discussed.
Biphenyl esters and liquid crystalline mixtures comprising them
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, (2008/06/13)
Biphenyl esters of the formula STR1 wherein X is --CO--O-- or --O--CO-- and R1 and R2 each are alkyl or alkoxy of 1 - 8 carbon atoms, enlarge significantly the temperature range of the nematic phase of liquid-crystalline compositions without adversely affecting other properties.
