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HEXAMETHYLPHOSPHOROUS TRIAMIDE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

59758-27-9

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59758-27-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 59758-27-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,9,7,5 and 8 respectively; the second part has 2 digits, 2 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 59758-27:
(7*5)+(6*9)+(5*7)+(4*5)+(3*8)+(2*2)+(1*7)=179
179 % 10 = 9
So 59758-27-9 is a valid CAS Registry Number.

59758-27-9Relevant academic research and scientific papers

Effect of isopropyl group on phosphorylation of phenols with phosphorous amides

Nifant'ev,Suvorkin,Rasadkina,Selyutina,Shishin

, p. 1183 - 1185 (2002)

Reaction of resorcinol with phosphorous triamides containing various aliphatic radicals was studied. The preferential cleavage from phosphorus of the diisopropylamino group compared with the less bulky dimethylamino group was observed for the first time. It was shown that resorcinol is easily phosphorylated under mild conditions independent of the nature of substituent on nitrogen, but sterically hindered bulky radicals on nitrogen slow down phenolysis not only of the first, but also of the second amido group.

Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

Rasadkina,Slitikov,Nifant'ev

, p. 183 - 197 (2008/02/08)

The dismutation of arylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined. Pleiades Publishing, Inc., 2006.

Dismutation of diamidoarylphosphites

Nifantyev, Edward E.,Rasadkina, Elena N.,Slitikov, Pavel V.,Vasyanina, Larisa K.

, p. 2465 - 2477 (2007/10/03)

Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.

Reaction of Phosphorous Tris(N-methyl-N-trifluoroacetylamides) with Amines

Sinitsa,Nesterova,Malenko,Luk'yanenko

, p. 62 - 64 (2007/10/03)

In reactions of phosphorous tris(N-methyl-N-trifluoroacetylamido)phosphite with sterically hindered primary amines, the amide group behaves as a pseudohalide group. These reactions can be used for preparing two-coordinate phosphorus compounds.

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