5977-82-2Relevant academic research and scientific papers
Palladium-catalyzed formation of 3,5-diaryl-1,2,4-selenadiazoles from arylselenocarboxamide
Al-Rubaie, Ali Z.,Yousif, Lina Z.,Al-Hamad, Ali J.H.
, p. 274 - 280 (2002)
A number of new and known arylselenocarboxamides (i.e. Ar-C(=Se)NH2; Ar=C6H5 (1), 4-BrC6H4 (2), 2-MeOC6H4 (3), 4-MeOC6H4 (4), 4-MeSC6H4/sub
Facile synthesis of selenocarboxamides from nitriles using Se/CO/H 2O under atmospheric pressure
Chen, Yahong,Tian, Fengshou,Song, Maoping,Lu, Shiwei
, p. 211 - 214 (2008)
Aromatic and aliphatic nitriles can be conveniently converted into the corresponding selenocarboxamides with Se/CO/H2O under atmospheric pressure without use of a base.
A synthetic and structural study of arylselenoamides and 2,4-diaryl-1,3- selenazoles
Hua, Guoxiong,Du, Junyi,Slawin, Alexandra M. Z.,Woollins, J. Derek
supporting information, p. 2189 - 2195 (2014/11/08)
The systematic preparation of 2,4-diaryl-1,3-selenazoles was carried out by two-component cyclization of the primary selenoamides with α-halo ketones. Selenoamides were obtained from the reaction of Woollins' reagent with arylnitrile, followed by hydrolys
Synthesis, characterization and antibacterial activity of some new ferrocenyl selenazoles and 3,5-diferrocenyl-1,2,4-selenadiazole
Al-Rubaie, Ali Z.,Al-Jadaan, Shaker A.S.,Muslim, Salah K.,Saeed, Eman A.,Ali, Eman T.,Al-Hasani, Amer K.J.,Al-Salman, Hussien N.K.,Al-Fadal, Sabaa A.M.
, p. 43 - 47 (2014/12/11)
New ferrocenyl containing selenazole derivatives were synthesized from reactions of aryl selenocarboxamide (i.e. Ar-CSe(NH2); ArC6H5 (1), 4-Br-C6H4 (2), 4-PhC6H4 (3), 4-CH3
Synthesis and antitumor-evaluation of 1,3-selenazole-containing 1,3,4-thiadiazole derivatives
Zhao, Hai-Chuan,Shi, Yan-Ping,Liu, Yu-Ming,Li, Cai-Wen,Xuan, Li-Na,Wang, Peng,Zhang, Kai,Chen, Bao-Quan
, p. 6577 - 6579 (2014/01/06)
A series of novel 1,3-selenazole-containing 1,3,4-thiadiazole derivatives bearing Schiff base moieties were synthesized and evaluated for their in vitro antiproliferative activities against human breast cancer cell MCF-7 and mouse lymphocyte leukemia cell
Synthesis of primary arylselenoamides by reaction of aryl nitriles with Woollins' reagent
Hua, Guoxiong,Li, Yang,Slawin, Alexandra M. Z.,Woollins, J. Derek
, p. 5251 - 5254 (2007/10/03)
The reaction of aryl nitriles with Woollins' reagent followed by water affords a variety of primary arylselenoamides In 60-100% yield. The first crystal structures of two primary selenoamides are reported.
Synthesis of 1,3-selenazoles and bis(selenazoles) from primary selenocarboxylic amides and selenourea
Geisler, Karlheinz,Pfeiffer, Wolf-Diethard,Kuenzler, Andreas,Below, Harald,Bulka, Ehrenfried,Langer, Peter
, p. 875 - 884 (2007/10/03)
The reaction of nitriles with P2Se5 in the presence of EtOH-H2O afforded primary selenocarboxylic amides. The cyclization of these compounds with α-halo ketones afforded a variety of functionalized 1,3-selenazoles. The use of P2Se5 also allowed the convenient synthesis of selenocarboxylic diamides which were transformed into bis(selenazol-2-yl)alkanes ('bis-selenazoles'). A practical method for the synthesis of selenourea was developed. This useful small building block was successfully applied to the synthesis of primary 2-amino-1,3- selenazoles.
Efficient synthesis of primary selenocarboxylic amides by reaction of nitriles with phosphorous(V) selenide
Geisler, Karlheinz,Jacobs, Anke,Künzler, Andreas,Mathes, Manuela,Girrleit, Ilona,Zimmermann, Birgit,Bulka, Ehrenfried,Pfeiffer, Wolf-Diethard,Langer, Peter
, p. 1983 - 1986 (2007/10/03)
The reaction of nitriles with P2Se5 in the presence of EtOH/H2O afforded a variety of primary selenocarboxylic amides.
Selenocarbonyl synthesis using Woollins reagent
Bhattacharyya, Pravat,Woollins
, p. 5949 - 5951 (2007/10/03)
[PhP(Se)(μ-Se)]2 selenates secondary and tertiary amides to the corresponding selenoamides in 30-70% yields at 130°C in toluene and indolizine-3-aldehydes to selenoaldehydes in 40-59% yield at 25°C.
A convenient synthesis of selenocarboxamides from nitriles
Kaminski,Glass,Skowronska
, p. 1308 - 1310 (2007/10/03)
Aromatic and aliphatic nitriles can be conveniently converted into the corresponding selenocarboxamides with monoselenophosphate in aqueous alcohol in 50-94% yield.
