59812-98-5

Basic information

• Product Name: [R,(-)]-2-Tridecanol
• Synonyms: (R)-2-Tridecanol;[R,(-)]-2-Tridecanol
• CAS NO: 59812-98-5
• Molecular Formula: C₁₃H₂₈O
• Molecular Weight: 200.36
• Mol File: 59812-98-5.mol
• Article Data: 30

Chemical Properties

• Appearance: /
• CAS DataBase Reference: [R,(-)]-2-Tridecanol(CAS DataBase Reference)
• NIST Chemistry Reference: [R,(-)]-2-Tridecanol(59812-98-5)
• EPA Substance Registry System: [R,(-)]-2-Tridecanol(59812-98-5)

Safety Data

• Hazardous Substances Data: 59812-98-5(Hazardous Substances Data)

Upstream product

• 593-08-8 tridecan-2-one 
• 112-54-9 Dodecanal 
• 74-88-4 methyl iodide 
• 111-82-0 methyl n-dodecanoate 
• 41446-59-7 (Z)-tridec-2-ene 
• 534-22-5 2-methylfuran 
• 140145-80-8 trans-2,3-Epoxy-1-tridecanol tosylate 
• 113466-78-7 (3-decyloxiran-2-yl)methyl 4-methylbenzenesulfonate 
• 113466-78-7 trans-2,3-Epoxy-1-tridecanol tosylate 
• 139926-08-2 trans-2,3-Epoxy-1-tridecyl chloride 
• 96562-66-2 tridec-12-en-2-ol 
• 143-07-7 lauric acid 
• 849585-22-4 LACTIC ACID 
• 117286-10-9 undecylmagnesium bromide 

Downstream Products

• 55193-07-2 Buttersaeure-2-tridecanester 
• 120876-13-3 (S)-(+)-1-methyldodecyl acetate 
• 140459-83-2 (R)-2-tridecanyl acetate 
• 1346758-16-4 1-methyldodecyl 3,5-dibromobenzoate 
• 41015-28-5 (+/-)-2-Tridecanyl acetate 
• 55193-94-7 Caprinsaeure-2-tridecylester 
• 593-08-8 tridecan-2-one 
• 61165-58-0 2-Tridecyl-p-dimethylamino-benzolsulfonat 

Relevant articles and documents

Zinc Hydride-Catalyzed Hydrofuntionalization of Ketones

Three new dimeric bis-guanidinate zinc(II) alkyl, halide, and hydride complexes [LZnEt]2 (1), [LZnI]2 (2) and [LZnH]2 (3) were prepared. Compound 3 was successfully employed for the hydrosilylation and hydroboration of a vast number of ketones. The catalytic performance of 3 in the hydroboration of acetophenone exhibits a turnover frequency, reaching up to 5800 h-1, outperforming that of reported zinc hydride catalysts. Notably, both intra- and intermolecular chemoselective hydrosilylation and hydroboration reactions have been investigated.

Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane

The highly enantioselective cobalt-catalyzed hydroboration reaction of aryl ketones with HBpin was developed using iminopyridine oxazoline ligands. Halides, amines, ethers, sulfides, esters and amides are well tolerated under the mild reaction conditions, demonstrating its synthetic advantage. Substituted diaryl ketones could also be hydroborated with high enantioselectivity.

Synthetic utility of tribenzyltin hydride and its derivatives as easily accessible, removable, and decomposable organotin reagents

Radical reactions using tribenzyltin hydride (Bn3SnH) easily prepared from tin and benzyl chloride were studied. The Et3B- initiated reduction and cyclization of haloalkanes and haloalkenes with Bn 3SnH proceeded efficiently. Homolytic hydrostannylation of alkynes with Bn3SnH followed by treatment with electrophiles gave functionalized alkenes in good to high yields. The organotin byproducts formed could be easily removable by filtration and silica-gel column chromatography without any pretreatment. It was also found that tribenzyltin chloride (Bn 3SnCl) easily decomposed to benzyl alcohol in a basic solution of H2O2.