5988-72-7

Upstream product

• 913815-70-0 (5R)-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate 
• 870-63-3 prenyl bromide 
• 75107-34-5 (R)-10-bromo-1⁽⁶⁾,8-p-menthadien-2-one 
• 89487-33-2 prenylmagnesium bromide 
• 6485-40-1 (R)-Carvone 
• 308363-12-4 L-carveol 
• 913815-73-3 C₁₆H₂₉OSiBr 
• 913815-72-2 C₁₆H₃₀OSi 
• 913815-71-1 sobrerol diacetate 
• 913815-74-4 C₂₁H₃₈OSi 

Relevant academic research and scientific papers

Determination of the absolute configuration of (+)-2,7(14),10- bisabolatrien-1-ol-4-one from Japanese cedar, Cryptomeria japonica

The absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one, a peculiar sesquiterpenol in the Japanese cedar, Cryptomeria japonica, was determined as (1S,6R)-2,7(14),10-bisabolatrien-1-ol-4-one by comparing the specific rotation values of crypto

Syntheses of bioactive bisabolane-type cryptomeria japonica sesquiterpenes

The first diastereoselective synthesis of (1S,6R)-1- hydroxy-2,7(14),10- bisabolatrien-4-one, an antifeedant against Acusta despesta and Locusta migratoria, was produced from Cryptomeria japonica (commonly known as Japanese cedar), starting from (R)-(-)-carvone via (R)-(-)-cryptomerione. The enantiomer was transformed into (1S,3R,6R)-1-hydroxy-7(14),10-bisaboladien- 4-one, a novel antifeedant against L. migratoria from the same tree, by 1,4-selective reduction of the enone moiety.

Selective synthesis of carvone and cryptomerlone from α-pinene

Carvone and cryptomerlone were synthesized selectively using electrochemical oxidation of α-pinene in the key step. 2006 Springer Science+Business Media, Inc.