75107-34-5

Upstream product

• 6485-40-1 (R)-Carvone 

Downstream Products

• 151910-94-0 (R)-(-)-2-Methyl-5-<1-(hydroxymethyl)vinyl>cyclohex-2-enon 
• 151894-32-5 (R)-(-)-Essigsaeure-<2-(4-methyl-5-oxo-cyclohex-3-enyl)allyl>ester 
• 898800-92-5 Acetic acid 2-((1R,5R)-5-hydroxy-4-methyl-cyclohex-3-enyl)-allyl ester 
• 898800-94-7 Acetic acid 2-((1S,3R,4R,5R)-3-bromo-4,5-dihydroxy-4-methyl-cyclohexyl)-allyl ester 
• 898801-06-4 Benzoic acid (3R,4R,5S)-5-(1-bromo-2-oxo-propyl)-4-methoxycarbonylmethyl-tetrahydro-furan-3-ylmethyl ester 
• 898800-91-4 Benzoic acid (3R,4R)-4-methoxycarbonylmethyl-5-[2-oxo-prop-(Z)-ylidene]-tetrahydro-furan-3-ylmethyl ester 
• 898801-05-3 Benzoic acid (3R,3aR,6R,7R,7aS)-7-bromo-6-hydroxy-6-methyl-5-oxo-octahydro-benzofuran-3-ylmethyl ester 
• 898801-02-0 Benzoic acid (3R,3aR,5R,6R,7R,7aS)-7-bromo-5,6-dihydroxy-6-methyl-octahydro-benzofuran-3-ylmethyl ester 
• 898801-01-9 Benzoic acid (3aR,4R,4aS,7R,7aR,8aR)-4-bromo-2,2,3a-trimethyl-octahydro-furo[2',3':4,5]benzo[1,2-d][1,3]dioxol-7-ylmethyl ester 
• 5988-72-7 (R)-cryptomerione 
• 1449386-01-9 C₂₉H₃₇N₃O₆Si 
• 1449385-78-7 C₁₈H₁₇NO₃ 

Relevant academic research and scientific papers

Total Synthesis of Highly Oxygenated Bisabolane Sesquiterpene Isolated from Ligularia lankongensis: Relative and Absolute Configurations of the Natural Product

The relative and absolute configurations of an oxygenated bisabolane natural product, isolated from Ligularia lankongensis, were determined by synthesis. All four possible stereoisomers and their tiglate analogues were synthesized from R-(-)-carvone, and their 1H and 13C NMR spectra were compared to establish the 6R,8S,10S configuration. The stereoselective synthesis of the natural product was also achieved, featuring Brown allylation, vanadium-catalyzed epoxidation, and the Mitsunobu reaction.

Stereoselective synthesis of (+)-paeonilide and confirmation of its absolute configuration

The first diastereoselective synthesis of paeonilide, a novel anti-PAF-active monoterpenoid, starting from R-(-)-carvone was reported. The absolute configuration for paeonilide was also established. Georg Thieme Verlag Stuttgart.

Determination of the absolute configuration of (+)-2,7(14),10- bisabolatrien-1-ol-4-one from Japanese cedar, Cryptomeria japonica

The absolute configuration of (+)-2,7(14),10-bisabolatrien-1-ol-4-one, a peculiar sesquiterpenol in the Japanese cedar, Cryptomeria japonica, was determined as (1S,6R)-2,7(14),10-bisabolatrien-1-ol-4-one by comparing the specific rotation values of crypto

Synthesis of Chiral Bicyclo[3.3.1]nonanes via a Tandem Intermolecular Alkylation-Intramolecular Michael Reaction Sequence

Stereo- and regioselective synthesis of chiral bicyclo[3.3.1]nonanes employing a tandem intermolecular alkylation and intramolecular Michael reaction sequence, starting from 10-bromocarvone derivatives and Michael donors is described.