599178-94-6

Basic information

• Product Name: 2^A-O-tert-butyldimethylsilyl-6^A-deoxy-S-phenyl-α-cyclodextrin
• Synonyms: 2^A-O-tert-butyldimethylsilyl-6^A-deoxy-S-phenyl-α-cyclodextrin
• CAS NO: 599178-94-6
• Molecular Weight: 1179.28
• Mol File: 599178-94-6.mol

Chemical Properties

• CAS DataBase Reference: 2^A-O-tert-butyldimethylsilyl-6^A-deoxy-S-phenyl-α-cyclodextrin(CAS DataBase Reference)
• NIST Chemistry Reference: 2^A-O-tert-butyldimethylsilyl-6^A-deoxy-S-phenyl-α-cyclodextrin(599178-94-6)
• EPA Substance Registry System: 2^A-O-tert-butyldimethylsilyl-6^A-deoxy-S-phenyl-α-cyclodextrin(599178-94-6)

Safety Data

• Hazardous Substances Data: 599178-94-6(Hazardous Substances Data)

Upstream product

• 930-69-8 sodium thiophenolate 
• 441764-43-8 mono-2-O-tert-butyldimethylsilyl-α-cyclodextrin 

Relevant articles and documents

Mechanism of 2-O→3-O silyl migration in cyclomaltohexaose (α-cyclodextrin)

To gain insight into the mechanism of the well-known 2-O→3-O silyl migration of 2-O-silylated cyclomaltooligosaccharides (cyclodextrins) under basic conditions, we have undertaken studies of the reaction of 2A-O-TBDMSi-6A-deoxy-6A-S-phenyl-α- cyclodextrin with MeI and NaH. Under these conditions, the TBDMSi group on the C-2 oxygen was found to migrate onto the C-3 oxygen in the glucose residue in which the C-2 oxygen is located, and not onto the C-3 oxygen in the adjacent glucose residue.