59950-11-7Relevant articles and documents
Tin-free radical carbonylation: Thiol ester synthesis using alkyl allyl sulfone precursors, phenyl benzenethiosulfonate, and CO
Kim, Sangmo,Kim, Sunggak,Otsuka, Noboru,Ryu, Ilhyong
, p. 6183 - 6186 (2007/10/03)
(Chemical Equation Presented) Remove contents from tin ... Thiol esters have been successfully synthesized through tin-free radical carbonylation (see scheme; V-40 = initiator). This approach can be further extended to sequential radical reactions involving cyclization, carbonylation, and trapping of acyl radicals by phenyl benzenethiosulfonate.
Radical reaction of S-phenyl chlorothioformate with alkyl iodides: Free radical-mediated carboxylation approach
Kim, Sunggak,Jon, Sang Yong
, p. 815 - 816 (2007/10/03)
Free radical-mediated carboxylation is achieved by treatment of alkyl iodides with S-phenyl chlorothioformate and bis(tributyltin) with irradiation at 300 nm.