59950-92-4

Upstream product

• 100-46-9 benzylamine 
• 53640-96-3 diethyl N-benzylphosphoramidate 
• 106-96-7 propargyl bromide 

Downstream Products

• 107343-44-2 N-benzyl N-(cyclohexyl-3-propene-2-yl) diethoxyphosphoramide (Z) 
• 132281-30-2 diethyl N-benzyl-N-(2-carboxyethyl)phosphoramidate 
• 132281-35-7 diethyl N-benzyl-N-[2-(methoxycarbonyl)ethyl]phosphoramidate 
• 131294-34-3 Benzyl-(3-oxo-propyl)-phosphoramidic acid diethyl ester 
• 131294-43-4 Benzyl-(2-oxo-propyl)-phosphoramidic acid diethyl ester 
• 132281-26-6 Benzyl-(3-trimethylsilanyl-prop-2-ynyl)-phosphoramidic acid diethyl ester 

Relevant academic research and scientific papers

HYDROBORATION D'AMINES INSATUREES. XI.REGIO- ET STEREOSELECTIVITE DES HYDRURES DU BORE VIS A VIS D'AMINES PROPARGYLIQUES N-PHOSPHORYLEES

The regioselectivity and the stereoselectivity of the hydroboration of N-alkylallylphosphoramide was examined.This study shows the preferential formation of γ-boron derivatives (90 to 100percent) and the excellent stereospecificity of the reaction (100percent (Z) configuration).The PIV-N bond hinders the nitrogen-boron coordination which is responsible for the anomalous behavior of N-propargylic amines towards hydroboration and allows the same regio- and stereo-selectivity as for alkynes.The iodination of boron derivatives leads, with good yields, to N-phosphoryl-β-ethylenic amines.