59964-41-9Relevant academic research and scientific papers
Selective synthesis of 1,2- cis -α-glycosides without directing groups. Application to iterative oligosaccharide synthesis
Chu, An-Hsiang Adam,Nguyen, Son Hong,Sisel, Jordan A.,Minciunescu, Andrei,Bennett, Clay S.
supporting information, p. 2566 - 2569 (2013/06/27)
A method for the highly selective synthesis of 1,2-cis-α-linked glycosides that does not require the use of the specialized protecting group patterns normally employed to control diastereoselectivity is described. Thioglycoside acceptors can be used, permitting iterative oligosaccharide synthesis. The approach eliminates the need for lengthy syntheses of monosaccharides possessing highly specialized and unconventional protecting group patterns.
Synthesis of a novel pentasaccharide core component from the lipooligosaccharide of Moraxella catarrhalis
Pearson, Andrew G.,Peak, Ian R.,Wilson, Jennifer C.,Grice, I. Darren
experimental part, p. 2805 - 2811 (2012/01/02)
The novel pentasaccharide [p-(trifluoroacetamido)phenyl]ethyl 3-O-β-d-glucopyranosyl-4-O-β-d-glucopyranosyl-6-O-[2-O-(α-d- glucopyranosyl)-β-d-glucopyranosyl]-α-d-glucopyranoside (1), which includes a linker moiety to enable facile coupling to an antigeni
Why are the hydroxy groups of partially protected N-acetylglucosamine derivatives such poor glycosyl acceptors, and what can be done about it? A comparative study of the reactivity of N-acetyl-, N-phthalimido-, and 2-azido-2-deoxy-glucosamine derivatives
Crich,Dudkin
, p. 6819 - 6825 (2007/10/03)
Competition experiments were used to determine that the 4-OH of a 2-deoxy-2-azidoglucose derivative is more reactive than that of the corresponding N-phthalimido glucose derivative which, in turn, is more easily glycosylated than the N-acetyl derivative.
