59965-19-4

Upstream product

• 1117-60-8 (R)-3,7-dimethyloctan-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 1117-61-9 (3R)-citronellol 
• 33885-93-7 (+)(R)-2.6-dimethyl-octanoic acid-⁽⁸⁾-nitrile 
• 32531-52-5 (R)-3,7-dimethyloctanoic acid 
• 59965-17-2 (R)-1-tert-butoxy-2,6-dimethyl-heptane 
• 123-51-3 i-Amyl alcohol 
• 2431-75-6 isoamyl tosylate 

Downstream Products

• 6750-34-1 (3R,7R)-hexahydrofarnesol 
• 1318253-54-1 3,4,5-tris((R)-3,7-dimethyloctyloxy)benzoic acid methyl ester 
• 1318253-53-0 C₃₆H₆₇NO₃ 
• 131636-84-5 (2R,6R,10R)-6,10,14-trimethyl-5-(phenylsulfonyl)-2-(tetrahydropyranyloxy)pentadecane 
• 131636-84-5 (2S,6R,10R)-6,10,14-trimethyl-5-(phenylsulfonyl)-2-(tetrahydropyranyloxy)pentadecane 
• 131636-77-6 (2S,6R)-2,6,10-trimethyl-3-(phenylsulfonyl)-1-(tetrahydropyranyloxy)undecane 
• 131636-78-7 (2R,6R)-2,6,10-trimethylundecyl tosylate 
• 131636-82-3 (2R,6R)-2,6,10-trimethyl-1-(phenylsulfonyl)undecane 
• 131636-80-1 (2R,6R)-2,6,10-trimethyl-1-(phenylthio)undecane 

Relevant academic research and scientific papers

Effect of stereogenic centers on the self-sorting, depolymerization, and atropisomerization kinetics of porphyrin-based aggregates

We present our results on the mixing of different porphyrin molecules in supramolecular assemblies. Herein, chiral amplification experiments reveal the subtle role of the structural (mis)match between these monomers. We show that according to the "sergean

Pheromone Synthesis, CXXVI. Synthesis and Biological Activity of Four Stereoisomers of 6,10,14-Trimethyl-2-pentadecanol, the Female-Produced Sex Pheromone of Rice Moth (Corcyra cephalonica)

The synthesis of four stereoisomers of the female-produced sex pheromone of the rice moth (Corcyra cephalonica) was achieved by starting from (R)-2a, (R)- or (S)-3a, and (R)- or (S)-4 and using alkylation of alkyl phenyl sulfones as the coupling reaction.Behavioral bioassy of each isomer revealed (2R,6R,10R)-1a to be eight times more active than a diastereomeric mixture of equal amounts of the eight possible stereoisomers, indicating that (2R,6R,10R)-1a is probably the natural pheromone or at least themajor component of the female blend.Electrophysiological bioassy also confirmed the high activity of (2R,6R,10R)-1a.

Intermediates in the synthesis of vitamin E

A synthesis of vitamin E in racemic or optically active forms from methacryolein or beta-hydroxyisobutyric acid including intermediates in this synthesis.