60031-12-1

Basic information

• Product Name: 2-benzylidene-5-nitro-1-indanone
• CAS NO: 60031-12-1
• Molecular Weight: 265.268
• Mol File: 60031-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-benzylidene-5-nitro-1-indanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-benzylidene-5-nitro-1-indanone(60031-12-1)
• EPA Substance Registry System: 2-benzylidene-5-nitro-1-indanone(60031-12-1)

Safety Data

• Hazardous Substances Data: 60031-12-1(Hazardous Substances Data)

Upstream product

• 22246-24-8 5-nitro-2,3-dihydroinden-1-one 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Asymmetric Cross [10+2] Cycloadditions of 2-Alkylidene-1-indanones and Activated Alkenes under Phase-Transfer Catalysis

Isobenzofulvene species are versatile synthons in organic chemistry, which have been employed in diverse challenging higher-order cycloaddition reactions. Here, the first chemoselective and asymmetric cross [10+2] cycloaddition reaction between activated 2-alkylidene-1-indanones and a variety of electron-deficient alkenes has been developed, relying on the in situ generation of dearomative 1-hydroxyl isobenzofulvene anion intermediates under the catalysis of a newly designed bulky cinchona-derived phase-transfer compound. An array of fused frameworks with multifunctionalities were generally furnished in excellent diastereo- and enantioselectivity, even at 1 mol % catalyst loadings.