600715-00-2

Upstream product

• 600714-98-5 C₆₄H₁₀₂O₆Si₄ 
• 600714-95-2 (Z)-(3S,4S,5R,6S,8S,11S,12S,13S)-6-(tert-Butyl-dimethyl-silanyloxy)-8,14-bis-(tert-butyl-diphenyl-silanyloxy)-12-methoxymethoxy-3,5,11,13-tetramethyl-tetradeca-1,9-dien-4-ol 
• 600714-96-3 (Z)-(3S,4R,5R,6S,8S,11S,12S,13S)-6-(tert-Butyl-dimethyl-silanyloxy)-8,14-bis-(tert-butyl-diphenyl-silanyloxy)-12-methoxymethoxy-3,5,11,13-tetramethyl-tetradeca-1,9-dien-4-ol 
• 600714-94-1 C₅₅H₈₂O₅Si₃ 
• 1026877-90-6 (Z)-(2S,3S,5S,8S,9S,10S)-3-(tert-Butyl-dimethyl-silanyloxy)-5,11-bis-(tert-butyl-diphenyl-silanyloxy)-9-methoxymethoxy-2,8,10-trimethyl-undec-6-enal 
• 600714-93-0 (Z)-(3R,4S,6S,9S,10S,11S)-6,12-Bis-(tert-butyl-diphenyl-silanyloxy)-10-methoxymethoxy-3,9,11-trimethyl-dodeca-1,7-dien-4-ol 
• 600714-91-8 C₄₆H₆₂O₄Si₂ 
• 600714-92-9 (Z)-(3S,6S,7S,8S)-3,9-Bis-(tert-butyl-diphenyl-silanyloxy)-7-methoxymethoxy-6,8-dimethyl-non-4-enal 
• 600714-87-2 2,2-Dimethyl-propionic acid (Z)-(4S,5S,6S)-7-(tert-butyl-diphenyl-silanyloxy)-5-methoxymethoxy-4,6-dimethyl-hept-2-enyl ester 
• 600714-90-7 (Z)-(4S,7S,8S,9S)-10-(tert-Butyl-diphenyl-silanyloxy)-8-methoxymethoxy-7,9-dimethyl-deca-1,5-dien-4-ol 
• 468738-71-8 (1S,2S)-1-{(1S)-2-[(tert-butyldiphenylsilyl)oxy]-1-methylethyl}-2-methylbut-3-enyl prop-2-enoate 
• 235099-38-4 (5S,6S)-6-{(1S)-2-[(tert-butyldiphenylsilyl)oxy]-1-methylethyl}-5-methyl-5,6-dihydro-2H-pyran-2-one 
• 106357-24-8 (3S,4S,5S)-6-(tert-butyldiphenylsiloxy)-4-hydroxy-3,5-dimethylhexan-1-ene 
• 92817-88-4 (2S)-3-{[tert-butyl(diphenyl)silyl]oxy}-2-methylpropanal 

Relevant academic research and scientific papers

Stereoselective synthesis of the C1-C13 fragment of (+)-discodermolide using asymmetric allyltitanations

(Matrix presented) The synthesis of the C1-C13 fragment of (+)-discodermolide has been achieved. The configurations of the stereogenic centers have been controlled by enantioselective allyl- and crotyltitanations of aldehydes, and the Z configuration of t