6008-83-9

Basic information

• Product Name: Furan-2-carbaldehyde ethane-1,2-diyl dithioacetal
• Synonyms: 2-(1,3-Dithiolane-2-yl)furan;2-(2-Furanyl)-1,3-dithiolane;2-(2-Furyl)-1,3-dithiolane;Furan-2-carbaldehyde (ethane-1,2-diyl)dithioacetal;Furan-2-carbaldehyde ethane-1,2-diyl dithioacetal
• CAS NO: 6008-83-9
• Molecular Formula: C7H8OS2
• Molecular Weight: 172.2678
• Mol File: 6008-83-9.mol
• Article Data: 48

Chemical Properties

• Boiling Point: 284.6°Cat760mmHg
• Flash Point: 125.9°C
• Appearance: /
• Density: 1.279g/cm³
• Vapor Pressure: 0.00506mmHg at 25°C
• Refractive Index: 1.613
• CAS DataBase Reference: Furan-2-carbaldehyde ethane-1,2-diyl dithioacetal(CAS DataBase Reference)
• NIST Chemistry Reference: Furan-2-carbaldehyde ethane-1,2-diyl dithioacetal(6008-83-9)
• EPA Substance Registry System: Furan-2-carbaldehyde ethane-1,2-diyl dithioacetal(6008-83-9)

Safety Data

• Hazardous Substances Data: 6008-83-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthetic Communications, 26, p. 1579, 1996 DOI: 10.1080/00397919608003526

InChI:InChI=1/C7H8OS2/c1-2-6(8-3-1)7-9-4-5-10-7/h1-3,7H,4-5H2

Upstream product

• 769-70-0 2-(furan-2-yl)-1,3-dioxane 
• 540-63-6 ethane-1,2-dithiol 
• 88-14-2 2-furanoic acid 
• 13529-27-6 2-(diethoxymethyl)furan 
• 1708-41-4 2-(furan-2-yl)-1,3-dioxolane 
• 98-01-1 furfural 
• 109-80-8 1.3-propanedithiol 

Downstream Products

• 98-01-1 furfural 

Relevant articles and documents

Bio-based bisfuran: Synthesis, crystal structure, and low molecular weight amorphous polyester

Discovery of renewable monomer feedstocks for fabrication of polymeric demand is critical in achieving sustainable materials. In the present work we have synthesized bisfuran diol (BFD) monomer from furfural, over four steps. BFD was examined via X-ray crystallography to understand the molecular arrangement in space, hydrogen bonding, and packing of the molecules. These data were further used to compare BFD with structurally related bisphenol A (BPA), and its known derivatives to predict the potential estrogenic or anti-estrogenic activities in BFD. Further, BFD was reacted with succinic acid to generate polyester material, bisfuran polyester (BFPE-1). MALDI characterization of BFPE-1 indicates low molecular weight polyester and thermal analysis reveals amorphous nature of the material.

Indium-Catalyzed Reductive Dithioacetalization of Carboxylic Acids with Dithiols: Scope, Limitations, and Application to Oxidative Desulfurization

In this study an InI3-TMDS (1,1,3,3-tetramethyldisiloxane) reducing system effectively catalyzed the reductive dithioacetalization of a variety of aromatic and aliphatic carboxylic acids with 1,2-ethanedithiol or 1,3-propanedithiol leading to the one-pot preparation of either 1,3-dithiolane derivatives or a 1,3-dithiane derivative. Also, the intact indium catalyst continuously catalyzed the subsequent oxidative desulfurization of an in situ formed 1,3-dithiolane derivative, which led to the preparation of the corresponding aldehydes.

Amorphous polyester from bio-based bis-furan assembly

Polymers, including Polyesters and Polycarbonates comprising residue of bis-furan diol, which is produced from renewable furfural feedstock and methods of making and using of those polyesters and polycarbonates are described. The method includes reacting a bis-furan diol with a dicarboxylic acid in the presence of a carbodiimide to produce the bis-furan containing polymers. In certain embodiments, the dicarboxylic acid is succinic acid; the bis-furan diol is the 5,5′-(propane-2,2-diyl)bis(furan-2,5-diyl) dimethanol and the carbodiimide is of N,N-diisopropylcarbodiimide.