60111-69-5

Usage

Uses

Used in Organic Synthesis:
BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II is employed as a reagent for the introduction of trimethylsilylmethyl groups to a variety of organic substrates. Its ability to facilitate such modifications makes it a valuable asset in the synthesis of complex organic molecules.
Used in Semiconductor Industry:
In the realm of semiconductors, BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II is utilized for the production of germanium-based materials. These materials exhibit distinctive electronic and optical properties, which are beneficial for the development of advanced semiconductor devices and technologies.
Used in Chemical and Material Science Applications:
Due to its stability and compatibility with a broad spectrum of solvents and reaction conditions, BIS[BIS(TRIMETHYLSILYL)METHYL]-GERMANIUM II serves as a versatile tool in chemical and material science research and development. Its adaptability allows for its use in numerous experimental setups and processes.

InChI:InChI=1/C14H40GeSi4/c1-16(2,3)13(17(4,5)6)15-14(18(7,8)9)19(10,11)12/h13-14H,15H2,1-12H3

Upstream product

• 62487-23-4 bis[bis(trimethylsilyl)methyl]germanium(II) dimer 
• 401587-52-8 (C₆H₅C(C₆H₅)O)Ge(CH(Si(CH₃)3)2)2 

Downstream Products

• 586418-36-2 (((CH₃)3Si)2CH)2GeIC₄H₉ 
• 586418-37-3 (((CH₃)3Si)2CH)2GeIC₄H₉ 
• 71-43-2 benzene 
• 586418-35-1 [(Me₃Si)2CH]2GeI(Ph) 
• 586418-33-9 (((CH₃)3Si)2CH)2GeIC₅H₉ 
• 401587-63-1 C₆H₅CNHGe(CH(Si(CH₃)3)2)2C₆H₅ 
• 401587-59-5 ClC₆H₄COGe(CH(Si(CH₃)3)2)2C₆H₄Cl 
• 586418-25-9 (((CH₃)3Si)2CH)2GeI(C₄H₇O) 
• 586418-32-8 (((CH₃)3Si)2CH)2GeI(C₄H₇O₂) 
• 586418-31-7 (((CH₃)3Si)2CH)2GeI(C₂H₅OCHCH₃) 
• 401587-61-9 CH₃C₆H₄COGe(CH(Si(CH₃)3)2)2C₆H₄CH₃ 
• 156298-12-3 C₄H₂GeN(O)2(C₆H₅)(CH(Si(CH₃)3)2)2 
• 153970-04-8 (C₆H₂(CH₃)3)2Si(N₃)NGe(CH(Si(CH₃)3)2)2 
• 156783-37-8 (C₆H₅)2SiN(GeN₃(CH(Si(CH₃)3)2)2)N₃Si(C₆H₅)2NHGe(OH)(CH(Si(CH₃)3)2)2 

Relevant academic research and scientific papers

Subvalent Group 4B Metal Alkyls and Amides. Part 8. Germanium and Tin Carbene Analogues MR2 : Syntheses and Structures in the Gas Phase (Electron Diffraction); Molecular-orbital Calculations for MH2 and GeMe2

Bisgermanium, GeR2 , is conveniently prepared from GeCl2(diox) (diox = 1,4-dioxane) (for which an improved synthesis, from GeCl4 and SnHBun3, is reported) and 2MgCl(R)(OEt2), MgR2(diox)0.5, or MgR2(OEt

Quick, efficient conversion of phenones to conjugated trienes via germylene cycloaddition

The conversion of phenones into conjugated trienes via germylene based cycloaddition reaction was investigated. The molecular modeling calculations based on DFT theory were performed to explore the comparative energetics of the formed products. The cycloaddition reaction at room temperature gave quantitative results that had some functional group tolerance.