Subvalent Group 4B Metal Alkyls and Amides. Part 8. Germanium and Tin Carbene Analogues MR2 : Syntheses and Structures in the Gas Phase (Electron Diffraction); Molecular-orbital Calculations for MH2 and GeMe2

DOI: 10.1039/DT9860001551

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1551 - 1556 (1986)

Update date:2022-08-17

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Authors:

Fjeldberg, Torgny

Haaland, Arne

Schilling, Birgitte E. R.

Lappert, Michael F.

Thorne, Andrew J.

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Article abstract of DOI:10.1039/DT9860001551

Bisgermanium, GeR2 , is conveniently prepared from GeCl2(diox) (diox = 1,4-dioxane) (for which an improved synthesis, from GeCl4 and SnHBuⁿ3, is reported) and 2MgCl(R)(OEt2), MgR2(diox)0.5, or MgR2(OEt

Full text of DOI:10.1039/DT9860001551

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