601488-57-7Relevant academic research and scientific papers
Donor-substituted perethynylated dehydroannulenes and radiaannulenes: Acetylenic carbon sheets featuring intense intramolecular charge transfer
Mitzel, Frieder,Boudon, Corinne,Gisselbrecht, Jean-Paul,Seiler, Paul,Gross, Maurice,Diederich, Francois
, p. 1130 - 1157 (2007/10/03)
In this article, we report the preparation of unprecedented φ-conjugated macrocycles (Fig. 1) by acetylenic scaffolding using modular tetraethynylethene (TEE, 3,4-diethynylhex-3-ene-1,5-diyne) building blocks. A novel photochemical access to (Z)-bisdeprot
Donor-substituted peralkynylated "radiaannulenes": Novel all-carbon macrocycles with an intense intramolecular charge-transfer
Mitzel, Frieder,Boudon, Corinne,Gisselbrecht, Jean-Paul,Seiler, Paul,Gross, Maurice,Diederich, Francois
, p. 1634 - 1635 (2007/10/03)
A novel class of planar, highly conjugated all-carbon macrocycles, which we christened "radiaannulenes", have been prepared based on acetylenic scaffolding using tetraethynylethene (TEE) building blocks; these structures are powerful electron acceptors an
