601488-61-3Relevant academic research and scientific papers
Donor-substituted perethynylated dehydroannulenes and radiaannulenes: Acetylenic carbon sheets featuring intense intramolecular charge transfer
Mitzel, Frieder,Boudon, Corinne,Gisselbrecht, Jean-Paul,Seiler, Paul,Gross, Maurice,Diederich, Francois
, p. 1130 - 1157 (2007/10/03)
In this article, we report the preparation of unprecedented φ-conjugated macrocycles (Fig. 1) by acetylenic scaffolding using modular tetraethynylethene (TEE, 3,4-diethynylhex-3-ene-1,5-diyne) building blocks. A novel photochemical access to (Z)-bisdeprot
π-electron conjugation effects in antiaromatic dehydro[12]- and aromatic dehydro[18]-annulenes
Mitzel, Frieder,Boudon, Corinne,Gisselbrecht, Jean-Paul,Gross, Maurice,Diederich, Francois
, p. 2318 - 2319 (2007/10/03)
N,N-Dimethylanilino-substituted perethynylated dehydro[12]- and dehydro[18]-annulenes were prepared by oxidative acetylenic coupling of cis-bisdeprotected tetra-ethynylethene derivatives obtained by a new photochemical route; they display strongly bathoch
