60164-93-4Relevant academic research and scientific papers
ENANTIOSPECIFIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXYLIDENE BROMOMETHANES
Solladie, Guy,Zimmermann, Richard G.
, p. 5769 - 5772 (2007/10/02)
Optically pure cyclohexylidene bromomethanes were prepared by stereospecific bromination alpha to a chiral sulfoxide, followed by the stereospecific pyrolytic elimination of the sulfoxide moiety.
ELECTRON TRANSFER FROM METAL SURFACES. FORMATION OF LITHIUM AND GRIGNARD REAGENTS.
Walborsky, H. M.,Banks, R. Bruce
, p. 849 - 868 (2007/10/02)
Chiral (+)-(S)-4-methylcyclohexylidenebromomethane (1) has been prepared from (-)-(R)-4-methylcyclohexylideneacetic acid by a stereospecific bromodecarboxylation reaction.The reaction was shown to proceed with an overall inversion of configuration.The rea
