60211-80-5Relevant articles and documents
Rearrangement reaction synthesized 3-furan-carbaldehyde compound of silver catalytic epoxy compound and application of 3-furan-carbaldehyde compound
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Paragraph 0020; 0021; 0022; 0023, (2017/02/17)
The invention discloses a rearrangement reaction synthesized 3-furan-carbaldehyde compound of a silver catalytic epoxy compound and application of the 3-furan-carbaldehyde compound. The 3-furan-carbaldehyde compound can be obtained with a 1-formyl-2-acete
Synthesis of 3-Formylfurans via a Silver(I)-Catalyzed Epoxide Ring-Opening/1,2-Acyl Migration/Cyclization Cascade
Wang, Jing,Shen, Chen,Wang, Tao,Mo, Sheng,Li, Xingxin,Zhang, Zunting
, p. 3943 - 3948 (2016/12/30)
By the design of suitable starting materials, a silver(I)-catalyzed epoxide ring-opening/1,2-acyl migration/cyclization cascade has been developed, which allowed us to systematically prepare unsymmetrical 3-formylfurans. Various 3-formylfurans were prepared in good to excellent yields. In addition, the distinct fluorescence properties of 3-formylfurans in solution and the solid state are disclosed. (Figure presented.).
Synthesis of highly substituted 3-formylfurans by a gold(I)-catalyzed oxidation/1,2-alkynyl migration/cyclization cascade
Wang, Tao,Shi, Shuai,Hansmann, Max M.,Rettenmeier, Eva,Rudolph, Matthias,Hashmi, A. Stephen K.
, p. 3715 - 3719 (2014/04/17)
3-Formylfuran derivatives are core structures of a variety of bioactive natural products. However, procedures for their preparation are still rare and generally inefficient in terms of atom economy: These methods require multiple steps or harsh reaction c
Synthesis of fully substituted 3-formyl-4-iodofurans via a gold(I)-catalyzed oxidation/1,2-alkynyl migration/cyclization/iodination cascade
Wang, Tao,Shi, Shuai,Rudolph, Matthias,Hashmi, A. Stephen K.
supporting information, p. 2337 - 2342 (2014/07/21)
A highly efficient gold(I)-catalyzed cascade reaction for the synthesis of fully substituted 3-formyl-4-iodofurans has been developed. Mechanistic investigations indicate a reaction pathway that involves a direct iodination reaction of the organogold intermediate via functionalization of the Au=C(sp2) bond, instead of a direct iodination of the 3-formylfurans.
Pd/Cu-catalyzed cascade Sonogashira coupling/cyclization reactions to highly substituted 3-formyl furans
Yang, Jingyu,Wang, Chengyu,Xie, Xin,Li, Hongfeng,Li, Ende,Li, Yanzhong
supporting information; experimental part, p. 1342 - 1346 (2011/04/16)
An efficient palladium/copper-catalyzed approach to the synthesis of highly substituted 3-formyl furans from the reactions of readily available α-bromoenaminones with terminal alkynes has been developed. This methodology was realized by the cascade reactions of Sonogashira coupling and the subsequent intramolecular cyclization. The Royal Society of Chemistry 2011.
A brief synthesis of β-iodofurans
Bew, Sean P.,Knight, David W.
, p. 1007 - 1008 (2007/10/03)
5-Endo-dig iodocyclisations of alk-3-yn-1,2-diols 4, followed by in situ dehydration, lead to good yields of β-iodofurans 5, which can subsequently be converted into a wide range of derivatives 6-13, using transition metal-catalysed coupling reactions or