60221-17-2

Basic information

• Product Name: 2-Dodecanol, 1-(phenylseleno)-
• CAS NO: 60221-17-2
• Molecular Formula: C18H30OSe
• Molecular Weight: 341.396
• Mol File: 60221-17-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Dodecanol, 1-(phenylseleno)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Dodecanol, 1-(phenylseleno)-(60221-17-2)
• EPA Substance Registry System: 2-Dodecanol, 1-(phenylseleno)-(60221-17-2)

Safety Data

• Hazardous Substances Data: 60221-17-2(Hazardous Substances Data)

Upstream product

• 112-44-7 undecylaldehyde 
• 20343-90-2 bis(phenylseleno)methane 
• 60221-21-8 1,1-bis(phenylseleno)heptane 
• 71098-88-9 N-phenylselanylphthalimide 
• 112-41-4 1-dodecene 
• 51-79-6 urethane 
• 1666-13-3 diphenyl diselenide 
• 2855-19-8 Decyl-oxiran 
• 645-96-5 Benzeneselenol 
• 67545-97-5 n-octyl phenyl selenoxide 
• 71766-38-6 Dodecyl phenyl selenoxide 
• 65275-53-8 β-Phenethyl-phenyl-selenoxid 
• 65275-52-7 Isobutyl(phenyl)selenoxid 
• 65275-51-6 n-propyl phenyl selenoxide 

Downstream Products

• 70677-95-1 1-(phenylseleno)-2-dodecanone 
• 702711-34-0 1-[(phenylseleno)methyl]undecylbenzoylcarbamate 

Relevant articles and documents

O-(tert-butyl) Se-phenyl selenocarbonate: A convenient, bench-stable and metal-free precursor of benzeneselenol

A study by our laboratory shows that air, light and moisture stable O-(tert-butyl) Se-phenyl selenocarbonate could be employed as a safer, practical and efficient alternative to generate “in situ” benzeneselenol or benzeneselenolate anion under different and transition metal-free conditions. This procedure seems to be of general application since the nucleophilic selenium species obtained can be trapped by electrophiles such as alkyl halides, epoxides and electron-deficient alkenes and alkynes under different reaction conditions.

Aminoselenenylation of Alkanes: Syntheses of β-Phenylseleno Carbamates and β-Phenylseleno Cyanamides

β-(Phenylseleno)alkylcarbamates and β-(phenylseleno)alkylcyanamides have been synthesized in good yields by reaction of alkenes with carbamates and cyanamide, respectively, in presence of benzeneselenenyl chloride-silver tetrafluoroborate or N-phenylselenophthalimide-H+.The subsequent reductive or oxidative removal of the phenylseleno group affords alkylcarbamates and alkylcyanamides, and allylic carbamates, cyanamides, and cyanimides.