60221-17-2Relevant academic research and scientific papers
O-(tert-butyl) Se-phenyl selenocarbonate: A convenient, bench-stable and metal-free precursor of benzeneselenol
Temperini, Andrea,Siciliano, Carlo
, (2020/06/17)
A study by our laboratory shows that air, light and moisture stable O-(tert-butyl) Se-phenyl selenocarbonate could be employed as a safer, practical and efficient alternative to generate “in situ” benzeneselenol or benzeneselenolate anion under different and transition metal-free conditions. This procedure seems to be of general application since the nucleophilic selenium species obtained can be trapped by electrophiles such as alkyl halides, epoxides and electron-deficient alkenes and alkynes under different reaction conditions.
A novel role of zeolite NaY in the thermal reaction of alkyl aryl selenoxides in its supercages
Zhang, Wanxuan,Yu, Haitao,Gao, Yu,Meng, Jiben,Matsuura, Teruo
, p. 498 - 499 (2007/10/03)
Thermal reaction of alkyl aryl selenoxides in the presence of water or methanol in the supercage of zeolite NaY gave β-hydroxy- or β-methoxyalkyl aryl selenides, respectively, and NaY played a novel role to stabilize reactive ArSeOH and to separate an anion of -OH from a carbonium ion which was simultaneously present with the -OH in a supercage.
Aminoselenenylation of Alkanes: Syntheses of β-Phenylseleno Carbamates and β-Phenylseleno Cyanamides
Francisco, Cosme G.,Hernandez, Rosendo,Leon, Elisa I.,Salazar, Jose A.,Suarez, Ernesto
, p. 2417 - 2427 (2007/10/02)
β-(Phenylseleno)alkylcarbamates and β-(phenylseleno)alkylcyanamides have been synthesized in good yields by reaction of alkenes with carbamates and cyanamide, respectively, in presence of benzeneselenenyl chloride-silver tetrafluoroborate or N-phenylselenophthalimide-H+.The subsequent reductive or oxidative removal of the phenylseleno group affords alkylcarbamates and alkylcyanamides, and allylic carbamates, cyanamides, and cyanimides.
