60221-21-8

Upstream product

• 111-71-7 heptanal 
• 645-96-5 Benzeneselenol 
• 108-86-1 bromobenzene 

Downstream Products

• 72335-28-5 3,3-Bis-phenylselanyl-nonan-1-ol 
• 62418-55-7 1-Phenylseleno-1-heptyl-trimethylsilan 
• 60245-62-7 8-(Phenylseleno)-7-tetradecanol 
• 61539-71-7 7,7-bis(phenylseleno) tridecane 
• 61539-99-9 (1-hexyl-heptylselanyl)-benzene 
• 60221-17-2 1-(phenylseleno)dodecan-2-ol 
• 63017-56-1 [((E)-Hept-1-enyl)selanyl]-benzene 
• 72335-29-6 1-Phenyl-2,2-bis-phenylselanyl-octan-1-ol 
• 28622-61-9 butyl phenyl selenide 
• 76376-91-5 n-heptyl phenyl selenide 
• 88088-13-5 2-(phenylseleno)octanal 
• 93578-92-8 (1-Allyl-heptylselanyl)-benzene 
• 31502-14-4 2-nonenyl alcohol 
• 88088-17-9 (1-Vinyl-heptylselanyl)-benzene 

Relevant academic research and scientific papers

C/Se bond cleavage of functionalized selenides by lithium arenides: Application to the geminal di-allylation of the carbonyl group of aldehydes and ketones

Selenoacetals as well as mixed (O,Se) acetals react with lithium arenides and produce, besides lithium selenolates, α-selenoalkyllithiums or α-alkoxyalkyllithiums respectively. We took advantage of these reactions as well as of the ones involving the synthesis of alkyllithiums from selenides to propose an original method for geminal di-allylation of the carbonyl group of aldehydes and ketones.

SYNTHESIS OF SELENOACETALS

This paper reports our results concerning the syntheses of various bis(alkylseleno)alkanes and some of their arylseleno analogues by different methods.The scope and limitation of each of them are presented.