602277-04-3

Upstream product

• 602276-98-2 C₁₉H₂₈O₅ 
• 602276-99-3 C₁₉H₃₀O₅ 
• 602277-02-1 C₁₉H₂₄O₃ 
• 602277-00-9 C₁₃H₂₂O₅ 
• 602277-01-0 C₁₃H₂₀O₃ 
• 23397-76-4 1,2:5,6-di-O-cyclohexylidene-α-D-glucofuranose 
• 18546-21-9 1,2:5,6-di-O-cyclohexylidene-α-D-ribo-3-hexofuranose-3-ulose 
• 602277-03-2 (3R,4S,5R)-2-Methoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan-3-ol 
• 74-88-4 methyl iodide 

Downstream Products

• 602277-09-8 tert-Butyl-((E)-(2R,3R,4S)-2,4-dimethoxy-1,3-dimethyl-6-phenyl-hex-5-enyloxy)-dimethyl-silane 
• 602277-08-7 (E)-(3S,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol 
• 602277-07-6 (E)-(3R,4R,5R)-6-(tert-Butyl-dimethyl-silanyloxy)-5-methoxy-4-methyl-1-phenyl-hept-1-en-3-ol 
• 602277-12-3 ((E)-(3S,4R,5R)-3,5-Dimethoxy-4,6-dimethyl-hepta-1,6-dienyl)-benzene 
• 602277-06-5 (E)-(3R,4R,5R)-3-Methoxy-4-methyl-7-phenyl-hept-6-ene-2,5-diol 
• 602277-10-1 (E)-(3R,4R,5S)-3,5-Dimethoxy-4-methyl-7-phenyl-hept-6-en-2-ol 
• 602277-11-2 (E)-(3R,4R,5S)-3,5-Dimethoxy-4-methyl-7-phenyl-hept-6-en-2-one 
• 307492-71-3 3,5-dimethoxy-2,4-dimethyl-7-phenyl-(2S,3S,4R,5S,6E)-6-hepten-1-ol 
• 602277-05-4 (3R,4R,5R)-3-Methoxy-4-methyl-5-((E)-styryl)-tetrahydro-furan-2-ol 

Relevant academic research and scientific papers

Carbohydrate-based synthesis of crocacin: Stereoselective Heck reaction of carbohydrate 5,6-ene- and 5,6-yne-derivatives with aromatic halides

The Heck reaction between a carbohydrate 5,6-ene derivative 9 and an aromatic halide exclusively gave rise to the β-carbohydrate-substituted trans-styrene derivative 8; while the corresponding Wittig reaction produced a cis/trans mixture in which the cis-

Functionality propagation by alkylative oxidation of cross-conjugated cycloheptadienyl sulfones

Getting the most out of sulfur. Enantiopure epoxyvinyl sulfone 1 is transformed to syn- and anti-dienyl sulfones 2 and 3, respectively, by means of a nucleophilic methylation/sulfenylation/directed elimination reaction sequence. Compound 2 has been converted into termini-differentiated seven-carbon polypropionate segments found in five biologically significant natural products.