602277-11-2Relevant academic research and scientific papers
Carbohydrate-based synthesis of crocacin: Stereoselective Heck reaction of carbohydrate 5,6-ene- and 5,6-yne-derivatives with aromatic halides
Gurjar, Mukund K.,Khaladkar, Tushar P.,Borhade, Ramdas G.,Murugan
, p. 5183 - 5187 (2007/10/03)
The Heck reaction between a carbohydrate 5,6-ene derivative 9 and an aromatic halide exclusively gave rise to the β-carbohydrate-substituted trans-styrene derivative 8; while the corresponding Wittig reaction produced a cis/trans mixture in which the cis-
