602307-73-3

Basic information

• Product Name: Carbamic acid, [(1S)-1-[(methoxyamino)carbonyl]-3-phenylpropyl]-, phenylmethyl ester
• CAS NO: 602307-73-3
• Molecular Formula: C19H22N2O4
• Molecular Weight: 342.395
• Mol File: 602307-73-3.mol

Chemical Properties

• CAS DataBase Reference: Carbamic acid, [(1S)-1-[(methoxyamino)carbonyl]-3-phenylpropyl]-, phenylmethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, [(1S)-1-[(methoxyamino)carbonyl]-3-phenylpropyl]-, phenylmethyl ester(602307-73-3)
• EPA Substance Registry System: Carbamic acid, [(1S)-1-[(methoxyamino)carbonyl]-3-phenylpropyl]-, phenylmethyl ester(602307-73-3)

Safety Data

• Hazardous Substances Data: 602307-73-3(Hazardous Substances Data)

Upstream product

• 288068-80-4 (2S)-2-benzyloxycarbonylamino-4-phenylbutyric acid ethyl ester 
• 74-88-4 methyl iodide 
• 501-53-1 benzyl chloroformate 
• 90891-21-7 L-(+)-α-amino-4-phenylbutyric acid ethyl ester hydrochloride 
• 83793-44-6 Z-homophenylalanine 
• 593-56-6 N-methoxylamine hydrochloride 

Downstream Products

• 602307-76-6 (5a-hydroxy-1-methoxy-2-oxo-2,3,4,5,5a,9a-hexahydro-1H-benzo[b]azepin-3-yl)-carbamic acid benzyl ester 

Relevant articles and documents

Palladium(ii)-catalyzed asymmetric C-H carbonylation to diverse isoquinoline derivatives bearing all-carbon quaternary stereocenters

Enantioselective synthesis of tetrahydroisoquinolines bearing an all-carbon quaternary stereogenic center, was achieved via asymmetric C-H activation with high enantioselectivities (up to 93% ee). Fair substrate tolerance was indicated throughout the scop

Synthesis of optically active α-aminobenzolactam via an oxidative-cyclization reaction

A convergent pathway for the asymmetric synthesis of (-)-α-aminobenzolactam 1 is described. For the first time, the key intermediate N-methoxybenzolactam 8 was prepared from L-homophenylalanine ethyl ester hydrochloride (LHPE·HCl) 5 by employing an oxidat