60253-06-7Relevant academic research and scientific papers
Metal-free cycloisomerizations of: O -alkynylbiaryls
Zhang, Jingyi,Li, Siqi,Qiao, Yan,Peng, Cheng,Wang, Xiao-Na,Chang, Junbiao
supporting information, p. 12455 - 12458 (2018/11/20)
We describe a novel and highly efficient metal-free strategy to construct 9,9-disubstituted fluorenes and phenanthrenes via the TfOH-catalyzed cycloisomerizations of o-alkynylbiaryls. Notably, the significant effects of the electronic properties and steric hindrance of the alkyne terminus on the reaction selectivity have been observed.
