Cas 603136-73-8,Ni(C6H5)2PCH2CH2PC6H5CH2CH2P(C6H5)2HCNC6H3(CH3)2(1+)

603136-73-8

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Basic information

Product Name: Ni(C₆H₅)2PCH₂CH₂PC₆H₅CH₂CH₂P(C₆H₅)2HCNC₆H₃(CH₃)2⁽¹⁺⁾
Synonyms: Ni(C₆H₅)2PCH₂CH₂PC₆H₅CH₂CH₂P(C₆H₅)2HCNC₆H₃(CH₃)2⁽¹⁺⁾
CAS NO:603136-73-8
Molecular Formula:
Molecular Weight: 725.432
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: Ni(C₆H₅)2PCH₂CH₂PC₆H₅CH₂CH₂P(C₆H₅)2HCNC₆H₃(CH₃)2⁽¹⁺⁾(CAS DataBase Reference)
NIST Chemistry Reference: Ni(C₆H₅)2PCH₂CH₂PC₆H₅CH₂CH₂P(C₆H₅)2HCNC₆H₃(CH₃)2⁽¹⁺⁾(603136-73-8)
EPA Substance Registry System: Ni(C₆H₅)2PCH₂CH₂PC₆H₅CH₂CH₂P(C₆H₅)2HCNC₆H₃(CH₃)2⁽¹⁺⁾(603136-73-8)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 603136-73-8(Hazardous Substances Data)

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603136-73-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 603136-73-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 6,0,3,1,3 and 6 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 603136-73:
(8*6)+(7*0)+(6*3)+(5*1)+(4*3)+(3*6)+(2*7)+(1*3)=118
118 % 10 = 8
So 603136-73-8 is a valid CAS Registry Number.

603136-73-8Upstream product

603136-73-8Downstream Products

603136-73-8Relevant academic research and scientific papers

Hydrocarbation chemistry proceeding from nickel carbenes

Hou, Hongyi,Gantzel, Peter K.,Kubiak, Clifford P.

, p. 9564 - 9565 (2003)

Nickel carbene complex 2 [Ni(triphos)C(H)N(H)xylyl]2+(BF4-)2 reacts with alkenes quantitatively and regiospecifically to give the anti-Markovnikov hydrocarbation products. X-ray crystallography shows significant iminium alkyl character of the hydrocarbation products, similar to that observed in parent carbene 2. Mechanistic studies suggest the importance of a hydride pathway over alkene (metallocycle formation or carbocation) pathways. Copyright

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