6037-42-9

Basic information

• Product Name: N-Acryloyl-N-methyl-α-phenylethylamine
• Synonyms: N-Acryloyl-N-methyl-α-phenylethylamine
• CAS NO: 6037-42-9
• Molecular Weight: 189.257
• Mol File: 6037-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-Acryloyl-N-methyl-α-phenylethylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-Acryloyl-N-methyl-α-phenylethylamine(6037-42-9)
• EPA Substance Registry System: N-Acryloyl-N-methyl-α-phenylethylamine(6037-42-9)

Safety Data

• Hazardous Substances Data: 6037-42-9(Hazardous Substances Data)

Upstream product

• 42882-26-8 N-methyl-N-(1-phenylethyl)amine 
• 814-68-6 acryloyl chloride 

Relevant articles and documents

SUPRAMOLECULAR ASYMMETRIC INDUCTION : A NEW CONCEPT APPLIED TO THE SUPPORTED ENANTIOSELECTIVE SYNTHESIS OF α-AMINO ACIDS

A polyacrylic resin with pendant chirality has been used as a chiral auxiliary.The prochiral ester enolate, reversibly linked to the polymer chain via a Schiff base, is surrounded by chiral pendants, allowing supramolecular asymmetric induction to occur.Amino acids with enantiomeric excesses up to 88-89percent could be synthesized from supported glycine t-butyl ester enolate by reaction with alkyl halides.Enantioselective protonation depends on the initial configuration of the supported amino acid.Alanine was obtained in 90percent ee by repetitive asymmetric protonation.