603963-41-3Relevant academic research and scientific papers
Nitrile oxide cycloadditions to olefinated sugars
Colinas, Pedro A.,J?ger, Volker,Lieberknecht, Albrecht,Bravo, Rodolfo D.
, p. 1071 - 1074 (2003)
Carbohydrate derivatives with a spiro-isoxazoline moiety as present in psammaplysins and ceratinamides (metabolites isolated from marine sponges) were prepared in good yields and excellent regio- and diastereoselectivity by a route involving Wittig olefination and 1,3-dipolar cycloaddition as key steps.
Synthesis of novel 2-deoxy-β-benzyl-C-glycosides by highly stereo- and chemoselective hydrogenation of exo-glycals
Díaz, Gisela,Ponzinibbio, Agustín,Bravo, Rodolfo Daniel
, p. 23 - 25 (2014/06/23)
Novel 2-deoxy-β-benzyl-C-glycosides were prepared in good yields and excellent stereoselectivity by a route involving the Wittig reaction of glycosyl phosphonium salts and reduction of exo-glycals as key steps. Hydrogenation of benzyl protected enol ethers was performed with Pd/C(en) as an effective chemoselective catalyst to afford exclusively β anomers.
