60428-22-0

Basic information

• Product Name: Benzene, (2-methyl-1-hexenyl)-, (Z)-
• CAS NO: 60428-22-0
• Molecular Formula: C13H18
• Molecular Weight: 174.286
• Mol File: 60428-22-0.mol

Chemical Properties

• CAS DataBase Reference: Benzene, (2-methyl-1-hexenyl)-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2-methyl-1-hexenyl)-, (Z)-(60428-22-0)
• EPA Substance Registry System: Benzene, (2-methyl-1-hexenyl)-, (Z)-(60428-22-0)

Safety Data

• Hazardous Substances Data: 60428-22-0(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 301298-28-2 1-tert-Butyldiphenylsilyl-1-phenylpropan-2-one 
• 917-54-4 methyllithium 
• 301298-30-6 1-tert-Butyldiphenylsilyl-1-phenylhexan-2-one 
• 100-52-7 benzaldehyde 
• 319488-97-6 P,P-diphenyl-P-(1-methylpentyl)(N-methoxycabonyl)phosphazene 
• 609815-80-7 2-butyl-2-methyl-3-phenylthiirane 
• 327619-22-7 thiophosphoric acid S-(1-benzoyl-1-methylpentyl) ester O,O-diethyl ester 
• 609815-93-2 Trimethyl-((E)-2-methyl-1-phenyl-hex-1-enyloxy)-silane 
• 3377-86-4 2-bromohexane 
• 105625-06-7 (1-methyl-pentyl)-diphenyl-phosphane 
• 263248-72-2 2-tert-Butyldiphenylsilyl-2-phenylethanal 
• 673-32-5 1-Phenylprop-1-yne 

Relevant articles and documents

Iron-catalyzed carbolithiation of alkynes having no heteroatoms

Alkyl- and aryllithium compounds were found to add to alkynes having no heteroatoms in the presence of an iron or iron-copper catalyst to give various trisubstituted vinyllithium compounds.

A general and stereoselective method for synthesis of tri- and tetrasubstituted alkenes

A convenient, general and stereoselective synthesis of trisubstituted alkenes and tetrasubstituted alkenes containing a cyanide function as well as trisubstituted episulphides have been elaborated. Methodology described for the preparation of these compounds is based on the corresponding readily available selenophosphates 1 and thiophosphates 2.

Synthesis of trisubstituted and tetrasubstituted alkenes via a manganate-induced migration-elimination process

Preparation of alkenes via a manganate-induced alkylation-elimination sequence was investigated. The reaction of 2-alkoxy-1,1-dibromoalkanes with trialkylmanganates afforded disubstituted or trisubstituted alkenes. Treatment of 2-alkoxy-1,1,1-tribromoalkanes with trialkylmanganates provided trisubstituted or tetrasubstituted alkenes through bromine-metal exchange, transfer of two alkyl groups from manganese to carbon, and successive elimination of metal and the β-alkoxy moieties.

Olefination reactions through phosphazenes

The first synthesis of di-, tri- and tetrasubstituted alkenes through reaction of lithium P-diphenyl(alkyl)(N-carboxymethyl)phosphazenes with aldehydes and ketones is reported.

The Peterson olefination using the tert-butyldiphenylsilyl group: Stereoselective synthesis of di- and trisubstituted alkenes

The reaction of α-tert-butyldiphenylsilyl carbonyl compounds with organometallics leads with a high diastereoselectivity to erythro-β-hydroxysilanes, which under acidic or basic elimination conditions give E or Z di- and trisubstituted alkenes.