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60465-14-7

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60465-14-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 60465-14-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,0,4,6 and 5 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 60465-14:
(7*6)+(6*0)+(5*4)+(4*6)+(3*5)+(2*1)+(1*4)=107
107 % 10 = 7
So 60465-14-7 is a valid CAS Registry Number.

60465-14-7Relevant articles and documents

Rhodium-Catalyzed Oxidative Coupling Reaction of Isocyanides with Alcohols or Amines and Molecular Oxygen as Oxygen Source: Synthesis of Carbamates and Ureas

Bu, Xiu-Bin,Wang, Zhuo,Wang, Yuan-Hong,Jiang, Tao,Zhang, Lu,Zhao, Yu-Long

, p. 1132 - 1138 (2017)

The first Rh-catalyzed aerobic oxidative coupling reaction of isocyanides with alcohols or amines has been developed. The reaction takes place under very mild conditions, by using air as the terminal oxidant and oxygen-atom source. It provides a simple, efficient, and general method for the construction of N-arylcarbamates and ureas in an atom-economic manner. Moreover, the new mechanism, involving α-diazocarbonyl compounds as carbene precursors and a RhI/RhIIIcatalytic cycle with oxygen, might open up new avenues in rhodium chemistry.

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