60466-42-4Relevant academic research and scientific papers
A simplified preparation of vinyl sulfides, selenides and tellurides by a Wittig-type reaction
Silveira, Claudio C.,Begnini, Mauro L.,Boeck, Paula,Braga, Antonio L.
, p. 221 - 224 (1997)
The preparation of several vinyl sulfides, selenides and tellurides by Wittig-type reaction in a one-pot procedure is described. The chalcogenyl triphenylphosphoranes 3 are formed 'in situ' by the reaction of chloromethyl phenyl chalcogenide, potassium tert-butoxide and triphenylphosphine. Reaction of 3 with carbonyl compounds affords the vinyl chalcogenides 6-9 with preferential Z-configuration.
