6047-92-3

Basic information

• Product Name: Cyclopropaneacetonitrile, a-oxo-
• CAS NO: 6047-92-3
• Molecular Formula: C5H5NO
• Molecular Weight: 95.1008
• Mol File: 6047-92-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Cyclopropaneacetonitrile, a-oxo-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropaneacetonitrile, a-oxo-(6047-92-3)
• EPA Substance Registry System: Cyclopropaneacetonitrile, a-oxo-(6047-92-3)

Safety Data

• Hazardous Substances Data: 6047-92-3(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 4023-34-1 cyclopropanecarboxylic acid chloride 

Relevant articles and documents

Trimethylsilyl Cyanide - A Reagent for Umpolung, VIII. Derivatives of 2-(Trimethylsilyloxy)-2-propenenitrile. Syntheses and General Properties

Rather different derivatives of the new title compuond 7 were synthesized by routes A - H (Table 2 and 3).The effects of substituents and reaction routes on the E/Z ratios (NMR) is discussed.Replacement of SiMe3 in 7 by RCO- and MeSO2- yields other alkenes with donor (O - X) and acceptor groups (CN) at the same C-atom.Their opposite effects on the β-C-atom is estimated from the corresponding 1H- and 13C-NMR signals.